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Shirayuki, a young herbalist born with unique apple-red hair. Bc if this unique hair a famous but foolish Prince Raji orders her to become his concubine. With nowhere else to go, Shirayuki cuts her hair and escapes to a neighboring country. While traversing through the forests, she meets a young man, Zen, who helps her after she boldly treat his wounds, but then gets poisoned by an apple meant for Shirayuki that was sent by Raij.
Akagami no Shirayukihime