#1 Kuroneko series
#2 Toshishita Kareshi no Renai Kanruguse -
http://www.mangago.me/read-manga/toshishita_kareshi_no_renai_kanriguse/
#3 Futari no Musuko ni Narawarete Imasu -
http://www.mangago.me/read-manga/futari_no_musuko_ni_nerawarete_imasu/
#4 Katekyo -
http://www.mangago.me/read-manga/katekyo/
Wow thats a hard question.
it depends on what factor it's base on.
in terms of feelings factor.
Junjou Romantica, mujihi no anata, and sekaiichi hatsuko
in terms of hotness factor
Escape Journey, Yondaime Ooyamato, Katekyo
Hello! Everyone comment on which manga/couple has the greatest sex ever! You can make out a list of top 3! Let the competition begin! ヾ(☆▽☆)