Now that u mention it I actually read something similar i was gonna rec but i cant find it
it's not as messy as this but the younger brother also was in love and quietly watches the one-sided unrequited love of his brother's friend.... i think they're roommates too..? Ugggh i cant remember at all.....
i have a list for similar tropes! https://www.mangago.me/home/mangalist/1689779/
but here are a few specific to relationships with the younger brother:
https://www.mangago.me/read-manga/deisui_shite_osotta/
https://www.mangago.me/read-manga/empty_heart/
https://www.mangago.me/read-manga/kare_ga_megane_o_hazusutoki/
https://www.mangago.me/read-manga/furimuite_tsukamaete/

I love stories like this, if anyone has recommends where it has to do with like the brothers friend, that they love, please recommend. But also, I really want another volume like this is so good.