This is what I have, I hope I understood you request correctly (*a lot of these are reverse harem because it's my personal preference, but I'm aware that most people don't like it so I labeled them with "RH" or "poly" if it has a poly ending)
Actual heavy smut but with a lot of plot as well:
https://www.mangago.me/read-manga/the_blood_of_madam_giselle/
https://www.mangago.me/read-manga/the_secret_bedroom_of_a_dejected_royal_daughter/ (RH)
https://www.mangago.me/read-manga/kill_my_husband/ (poly)
https://www.mangago.me/read-manga/concentration_of_malice_r19_version/ (RH)
https://www.mangago.me/read-manga/the_tainted_half_r15/ (RH)
https://www.mangago.me/read-manga/predator_marriage/
https://www.mangago.me/read-manga/the_fake_saint_waits_to_leave/ (poly)
https://www.mangago.me/read-manga/fire_in_the_swamp/
https://www.mangago.me/read-manga/tears_on_a_withered_flower/
https://www.mangago.me/read-manga/the_evil_grand_duchess_has_a_secret_life/ (poly)
https://www.mangago.me/read-manga/blood_kiss_r_19/ (RH)
https://www.mangago.me/read-manga/secret_histories_19_luna_toons/ (RH)
https://www.mangago.me/read-manga/the_only_way_to_achieve_world_peace_19_luna_toons/ (poly)
https://www.mangago.me/read-manga/the_beast_of_the_albard_mansion_19_eris_scans/
https://www.mangago.me/read-manga/i_love_handsome_nerdy_man_dindin/ (RH)
https://www.mangago.me/read-manga/valentina_s_paradise_19_luna_toons/
https://www.mangago.me/read-manga/the_princess_s_bedroom_doll_jyl/
https://www.mangago.me/read-manga/i_became_my_son_s_first_love/ (RH)
https://www.mangago.me/read-manga/altruistic_warrior/
https://www.mangago.me/read-manga/he_might_not_be_my_husband/
(in most of these they do it pretty early though)
Mature/suggestive scenes but with NO actual smut. Basically, they do it but it's only implied (these are probably closer to what you want):
https://www.mangago.me/read-manga/moral_less_scandal/ (the novel had actual smut scenes but the manhwa cut them off)
https://www.mangago.me/read-manga/a_wicked_husband/
https://www.mangago.me/read-manga/how_to_get_my_husband_on_my_side/
https://www.mangago.me/read-manga/who_stole_empress/
https://www.mangago.me/read-manga/taram_taram_taram/
https://www.mangago.me/read-manga/wake_up_warrior/ (poly)
https://www.mangago.me/read-manga/the_s_class_dungeon_owner/ (poly)
https://www.mangago.me/read-manga/to_the_noble_and_the_vile_you/ (in the novel they do it, after a looooong time though)
https://www.mangago.me/read-manga/the_butterfly_that_swallowed_fog/ (the novel had actual smut scenes but the manhwa cut them off)

is there any historical shoujo manga that has smut in it but the entire plot isnt smut. like they only do it when their relationship develops