This one: https://www.mangago.me/read-manga/i_favor_the_villainess/
oh and this one too: https://www.mangago.me/read-manga/akuyaku_reijou_desu_ga_hiroin_ni_kouryaku_sarete_masu_wa_anthology_comic/
not all of them are romantic, some are more vague, but you can interpret them as romantic
And a classic: https://www.mangago.me/read-manga/the_one_within_the_villainess/ (also not quite romantic but it's really interesting if you haven't read it yet (๑•ㅂ•)و✧)
It's...a little complicated. I personally don't think the love the mc has for 'Emi' is romantic, but it's definitely not your run of the mill relationship. But just know, all the mc cares about is Emi. She cares very little for others' feelings and emotions towards her
Of course, this is just a personal opinion.

can you guys help me finding ones when the villain and heroine get together and ditch the guy?ლ(´ڡ`ლ)